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Ligand–Metal Cooperating PC(sp 3 )P Pincer Complexes as Catalysts in Olefin Hydroformylation
Author(s) -
Musa Sanaa,
Filippov Oleg A.,
Belkova Natalia V.,
Shubina Elena S.,
Silantyev Gleb A.,
Ackermann Lutz,
Gelman Dmitri
Publication year - 2013
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201303311
Subject(s) - hydroformylation , ligand (biochemistry) , catalysis , olefin fiber , pincer movement , intramolecular force , chemistry , metal , combinatorial chemistry , computer science , rhodium , stereochemistry , organic chemistry , biochemistry , receptor
Ligand–metal cooperation : A new ligand–metal cooperating catalyst for the hydroformylation of olefins is described (see scheme). The mechanism of the H 2 activation and CH bond formation of the catalyst involves an intramolecular cooperation between the structurally remote functionality and the metal center and proceeds without change of the oxidation state of the metal.