β‐Type Glycosidic Bond Formation by Palladium‐Catalyzed Decarboxylative Allylation | Zendy

Xiang Shaohua | Zendy; Lu Zhiqiang | Zendy; He Jingxi | Zendy; Le MaiHoang Kim | Zendy; Zeng Jing | Zendy; Liu XueWei | Zendy

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β‐Type Glycosidic Bond Formation by Palladium‐Catalyzed Decarboxylative Allylation

Author(s) -

Xiang Shaohua,

Lu Zhiqiang,

He Jingxi,

Le MaiHoang Kim,

Zeng Jing,

Liu XueWei

Publication year - 2013

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201303241

Subject(s) - glycosidic bond , palladium , glycosylation , chemistry , stereoselectivity , glycoside , catalysis , organic chemistry , combinatorial chemistry , biochemistry , enzyme

Decarboxylative allylation of glycals : A β‐type glycosidic bond has been constructed in high regio‐ and stereoselectivity by means of a palladium‐catalyzed decarboxylative O ‐glycosylation. Various kinds of glycals with different protecting groups have been examined for this reaction to afford a diverse set of glycosylated products, including phenolic O ‐glycosides, thiophenolic S ‐glycoside, aliphatic O ‐glycosides, and disaccharides with excellent β‐selectivity and reasonable to excellent yields (see scheme).

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