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Full Sensitivity and Enhanced Resolution in Homodecoupled Band‐Selective NMR Experiments
Author(s) -
Castañar Laura,
Nolis Pau,
Virgili Albert,
Parella Teodor
Publication year - 2013
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201303235
Subject(s) - sensitivity (control systems) , resolution (logic) , nuclear magnetic resonance spectroscopy , pulse (music) , block (permutation group theory) , nuclear magnetic resonance , pulse sequence , spectroscopy , two dimensional nuclear magnetic resonance spectroscopy , materials science , optics , computer science , physics , electronic engineering , mathematics , engineering , geometry , artificial intelligence , detector , quantum mechanics
Fingers on the pulse : An NMR pulse scheme that provides full sensitivity in homodecoupled band‐selective NMR spectroscopy experiments is proposed (see figure). The easy implementation of this HOBS scheme as a general building block into a great variety of multidimensional NMR experiments leads to pure‐shift spectra with enhanced resolution and with the maximum attainable sensitivity.