Paradigm Shift from Alkaline (Earth) Metals to Early Transition Metals in Fluoroorganometal Chemistry: Perfluoroalkyl Titanocene(III) Reagents Prepared via Not Titanocene(II) but Titanocene(III) Species | Zendy

Fujiu Motohiro | Zendy; Hashimoto Ryota | Zendy; Nakamura Yuzo | Zendy; Aikawa Kohsuke | Zendy; Ito Shigekazu | Zendy; Mikami Koichi | Zendy

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Paradigm Shift from Alkaline (Earth) Metals to Early Transition Metals in Fluoroorganometal Chemistry: Perfluoroalkyl Titanocene(III) Reagents Prepared via Not Titanocene(II) but Titanocene(III) Species

Author(s) -

Fujiu Motohiro,

Hashimoto Ryota,

Nakamura Yuzo,

Aikawa Kohsuke,

Ito Shigekazu,

Mikami Koichi

Publication year - 2014

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201303089

Subject(s) - reagent , chemistry , alkaline earth metal , reactivity (psychology) , transition metal , medicinal chemistry , group 2 organometallic chemistry , inorganic chemistry , organic chemistry , alkali metal , catalysis , molecule , medicine , alternative medicine , pathology

Perfluoroalkyl (R F ) titanocene reagents [Cp 2 Ti III R F ] synthesized via [Cp 2 Ti III Cl] rather than [Cp 2 Ti II ] show new types of perfluoroalkylation reactions. The [Cp 2 Ti III R F ] reagents exhibit a wide variety of reactivity with carbonyl compounds including esters and nitriles, and selectivities far higher than those reported for conventional R F Li and R F MgX reagents.

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