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Ba 3 M 2 [B 3 O 6 (OH)] 2 [B 4 O 7 (OH) 2 ] (M=Al, Ga): Two Novel UV Nonlinear Optical Metal Borates Containing Two Types of Oxoboron Clusters
Author(s) -
Cheng Lin,
Wei Qi,
Wu HanQing,
Zhou LiuJiang,
Yang GuoYu
Publication year - 2013
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201303088
Subject(s) - acentric factor , crystallography , chemistry , computer science , mineralogy , physics
Two acentric metal borates Ba 3 M 2 ‐ [B 3 O 6 (OH)] 2 [B 4 O 7 (OH) 2 ] (M=Al, Ga) have been made under hydrothermal conditions; the MO 4 groups and two types of oxoboron cluster units interconnect to form a 3D porous layer with 9‐/14‐membered‐ring intersecting channels (see figure), showing a good second harmonic generation effect of about three times that of KH 2 PO 4 (KDP).