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Utilization of Common Ligands for the Ruthenium‐Catalyzed Amination of Alcohols
Author(s) -
Baumann Wolfgang,
Spannenberg Anke,
Pfeffer Jan,
Haas Thomas,
Köckritz Angela,
Martin Andreas,
Deutsch Jens
Publication year - 2013
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201302774
Subject(s) - ruthenium , amination , triphenylphosphine , denticity , catalysis , primary (astronomy) , chemistry , ligand (biochemistry) , combinatorial chemistry , organic chemistry , crystal structure , biochemistry , physics , receptor , astronomy
Simultaneous presence of bidentate phosphines with surprisingly simple structure and of the ligand triphenylphosphine were revealed as structural characteristics of new Ru catalysts for the selective conversion of primary and secondary alcohols and diols into their corresponding primary amines and diamines (see scheme).