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Molar‐Ratio‐Dependent Supramolecular Isomerism: Ag I Coordination Polymers with Bis(cyanobenzyl)sulfides
Author(s) -
Lee Eunji,
Kim JaYeon,
Lee Shim Sung,
Park KiMin
Publication year - 2013
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201302633
Subject(s) - supramolecular chemistry , molar ratio , ligand (biochemistry) , polymer , key (lock) , chemistry , content (measure theory) , metal , computer science , information retrieval , crystallography , organic chemistry , mathematics , crystal structure , biochemistry , receptor , catalysis , mathematical analysis , computer security
The ratio is the key : On varying the molar ratio of the reactants, AgNO 3 and tridentate m ‐ L ligand, supramolecular isomers 1 and 2 comprising a 2D polymeric network were obtained. Conformational differences of m ‐ L play a crucial role in the 2D network structures adopted for isomers 1 and 2 .