Molar‐Ratio‐Dependent Supramolecular Isomerism: Ag I  Coordination Polymers with Bis(cyanobenzyl)sulfides | Zendy

Lee Eunji | Zendy; Kim JaYeon | Zendy; Lee Shim Sung | Zendy; Park KiMin | Zendy

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Molar‐Ratio‐Dependent Supramolecular Isomerism: Ag I Coordination Polymers with Bis(cyanobenzyl)sulfides

Author(s) -

Lee Eunji,

Kim JaYeon,

Lee Shim Sung,

Park KiMin

Publication year - 2013

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201302633

Subject(s) - supramolecular chemistry , molar ratio , ligand (biochemistry) , polymer , key (lock) , chemistry , content (measure theory) , metal , computer science , information retrieval , crystallography , organic chemistry , mathematics , crystal structure , biochemistry , receptor , catalysis , mathematical analysis , computer security

The ratio is the key : On varying the molar ratio of the reactants, AgNO 3 and tridentate m ‐ L ligand, supramolecular isomers 1 and 2 comprising a 2D polymeric network were obtained. Conformational differences of m ‐ L play a crucial role in the 2D network structures adopted for isomers 1 and 2 .

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