Crystal and Electronic Structure of the Lithium‐Rich Silver Silicide Li 12 Ag 1− x  Si 4  ( x =0.15) | Zendy

Slabon Adam | Zendy; Budnyk Serhiy | Zendy; CuervoReyes Eduardo | Zendy; Wörle Michael | Zendy; Verel René | Zendy; Nesper Reinhard | Zendy

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Crystal and Electronic Structure of the Lithium‐Rich Silver Silicide Li 12 Ag 1− x Si 4 ( x =0.15)

Author(s) -

Slabon Adam,

Budnyk Serhiy,

CuervoReyes Eduardo,

Wörle Michael,

Verel René,

Nesper Reinhard

Publication year - 2013

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201302574

Subject(s) - silicide , lithium (medication) , crystallography , electronic structure , crystal structure , service (business) , materials science , chemistry , computer science , physics , silicon , condensed matter physics , optoelectronics , medicine , economy , economics , endocrinology

Zintl phases : The new lithium‐rich Zintl phase Li 12 Ag 1− x Si 4 ( x =0.15) contains the highly charged 16‐electron anion [AgSi 2 ] 7− . Chemical bonding is discussed based on electronic band structure analysis (see figure).

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