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Crystal and Electronic Structure of the Lithium‐Rich Silver Silicide Li 12 Ag 1− x Si 4 ( x =0.15)
Author(s) -
Slabon Adam,
Budnyk Serhiy,
CuervoReyes Eduardo,
Wörle Michael,
Verel René,
Nesper Reinhard
Publication year - 2013
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201302574
Subject(s) - silicide , lithium (medication) , crystallography , electronic structure , crystal structure , service (business) , materials science , chemistry , computer science , physics , silicon , condensed matter physics , optoelectronics , medicine , economy , economics , endocrinology
Zintl phases : The new lithium‐rich Zintl phase Li 12 Ag 1− x Si 4 ( x =0.15) contains the highly charged 16‐electron anion [AgSi 2 ] 7− . Chemical bonding is discussed based on electronic band structure analysis (see figure).