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General and Selective C‐3 Alkylation of Indoles with Primary Alcohols by a Reusable Pt Nanocluster Catalyst
Author(s) -
Siddiki S. M. A. Hakim,
Kon Kenichi,
Shimizu Kenichi
Publication year - 2013
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201302464
Subject(s) - alkylation , catalysis , primary (astronomy) , chemistry , organic chemistry , platinum , combinatorial chemistry , physics , astronomy
The platinum rule : Heterogeneous, additive‐free C‐3 selective alkylation of indoles by aliphatic and aromatic alcohols proceeded under transfer hydrogenation conditions with the reusable Pt/θ‐Al 2 O 3 catalyst (see scheme; TON=turnover number).