Electrochemical Synthesis of the Aryl α‐Ketoesters from Acetophenones Mediated by KI | Zendy

Zhang Zhenlei | Zendy; Su Jihu | Zendy; Zha Zhenggen | Zendy; Wang Zhiyong | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Electrochemical Synthesis of the Aryl α‐Ketoesters from Acetophenones Mediated by KI

Author(s) -

Zhang Zhenlei,

Su Jihu,

Zha Zhenggen,

Wang Zhiyong

Publication year - 2013

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201302307

Subject(s) - construct (python library) , electrochemistry , combinatorial chemistry , aryl , chemistry , computer science , transformation (genetics) , organic chemistry , programming language , electrode , biochemistry , alkyl , gene

Two CO bonds formed in one step : The oxidative coupling reaction of acetophenones with alcohol was developed by a dioxygen activation to afford α‐ketoesters under electrochemical conditions. This novel transformation not only provides a simple and efficient approach to synthetize α‐ketoester derivatives, but also invents a new strategy to construct a CO bond by virtue of an anode oxidation (see scheme).

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research