Synthesis of Alkylbismuths by Regiodivergent Carbobismuthination of Simple Alkenes | Zendy

Nishimoto Yoshihiro | Zendy; Takeuchi Midori | Zendy; Yasuda Makoto | Zendy; Baba Akio | Zendy

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Synthesis of Alkylbismuths by Regiodivergent Carbobismuthination of Simple Alkenes

Author(s) -

Nishimoto Yoshihiro,

Takeuchi Midori,

Yasuda Makoto,

Baba Akio

Publication year - 2013

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201302194

Subject(s) - regioselectivity , ketene , alkene , computer science , bismuth , acetal , simple (philosophy) , halogen , silylation , chemistry , combinatorial chemistry , organic chemistry , philosophy , catalysis , epistemology , alkyl

Switchable regioselectivity : This study represents the first carbobismuthination of alkenes achieved by the treatment of an alkene with a bismuth halide and a ketene silyl acetal. This reaction is particularly noteworthy in that a change in the type of halogen on a bismuth atom very easily switched the regioselectivity (see scheme).

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