CS Coupling Using a Mixed‐Ligand Pd Catalyst: A Highly Effective Strategy for Synthesizing Arylthio‐Substituted Heterocycles | Zendy

Cong Mei | Zendy; Fan Yuting | Zendy; Raimundo JeanManuel | Zendy; Xia Yi | Zendy; Liu Yang | Zendy; Quéléver Gilles | Zendy; Qu Fanqi | Zendy; Peng Ling | Zendy

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CS Coupling Using a Mixed‐Ligand Pd Catalyst: A Highly Effective Strategy for Synthesizing Arylthio‐Substituted Heterocycles

Author(s) -

Cong Mei,

Fan Yuting,

Raimundo JeanManuel,

Xia Yi,

Liu Yang,

Quéléver Gilles,

Qu Fanqi,

Peng Ling

Publication year - 2013

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201302174

Subject(s) - xantphos , catalysis , palladium , ligand (biochemistry) , combinatorial chemistry , halide , chemistry , coupling (piping) , organic chemistry , materials science , biochemistry , receptor , metallurgy

CS coupling : A variety of arylthio‐substituted heterocycles can be prepared through CS coupling of the corresponding halide‐substituted heterocycles by using a mixed‐ligand palladium catalyst, [Pd 2 (dba) 3 ]/ Xantphos/CyPF‐ t Bu (see scheme; dba=dibenzylideneacetone). This catalytic system is extremely powerful and efficient, allowing even CCl bond activation.

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