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The Lewis Base Stabilized Parent Arsanylborane H 2 AsBH 2 ⋅NMe 3
Author(s) -
Marquardt Christian,
Adolf Ariane,
Stauber Andreas,
Bodensteiner Michael,
Virovets Alexander V.,
Timoshkin Alexey Y.,
Scheer Manfred
Publication year - 2013
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201302110
Subject(s) - reactivity (psychology) , monomer , lewis acids and bases , yield (engineering) , base (topology) , computer science , service (business) , chemistry , database , organic chemistry , mathematics , materials science , business , catalysis , medicine , mathematical analysis , alternative medicine , pathology , marketing , polymer , metallurgy
Exclusively hydrogen‐substituted arsanylboranes : The synthesis of the unprecedented Lewis base stabilized monomeric parent compound of the arsanylborane H 2 AsBH 2 ⋅ NMe 3 was achieved in a one‐pot reaction in high yield and purity. The analogous phosphanylborane was synthesized in a similar manner. A series of different reactions was performed on H 2 AsBH 2 ⋅ NMe 3 to show its broad reactivity pattern.