A Novel Double Carbonylation Reaction of Aryl Halides: Selective Synthesis of 5‐Arylfuranones | Zendy

Schranck Johannes | Zendy; Wu XiaoFeng | Zendy; Tlili Anis | Zendy; Neumann Helfried | Zendy; Beller Matthias | Zendy

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A Novel Double Carbonylation Reaction of Aryl Halides: Selective Synthesis of 5‐Arylfuranones

Author(s) -

Schranck Johannes,

Wu XiaoFeng,

Tlili Anis,

Neumann Helfried,

Beller Matthias

Publication year - 2013

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201302092

Subject(s) - regioselectivity , novelty , aryl , carbonylation , halide , computer science , combinatorial chemistry , yield (engineering) , chemistry , organic chemistry , materials science , catalysis , alkyl , psychology , carbon monoxide , metallurgy , social psychology

Double CO inCOrporation : An atom‐efficient synthesis of 4‐arylfuranones from aryl halides, two molecules of CO, and terminal alkenes is reported (see scheme). 18 different 4‐arylfuranones were synthesized in up to 83 % yield in a straightforward manner and with high regioselectivity. The range of the new 4‐arylfuranones synthesized demonstrates the value and novelty of this procedure.

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