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Solid‐State Covalent Capture of CO 2 by Using N‐Heterocyclic Carbenes
Author(s) -
Vogt Monika,
Bennett Joshua E.,
Huang Yong,
Wu Chao,
Schneider William F.,
Brennecke Joan F.,
Ashfeld Brandon L.
Publication year - 2013
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201302013
Subject(s) - carbene , computer science , state (computer science) , service (business) , solid state , reagent , database , information retrieval , chemistry , organic chemistry , business , algorithm , catalysis , marketing
Capture me! The first report of an N‐heterocyclic carbene (NHC) as a solid‐state carbon capture reagent is presented. Experimental and theoretical measurements demonstrate the ability of the NHC to react rapidly and stoichiometrically with CO 2 at low partial pressures (see scheme).