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Quinonediimine‐Induced Oxidative Coupling of Organomagnesium Reagents
Author(s) -
Amaya Toru,
Suzuki Riyo,
Hirao Toshikazu
Publication year - 2014
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201301993
Subject(s) - reagent , oxidative phosphorylation , aryl , oxidative coupling of methane , chemistry , redox , polyaniline , unit (ring theory) , coupling (piping) , combinatorial chemistry , organic chemistry , materials science , psychology , biochemistry , catalysis , metallurgy , alkyl , polymer , mathematics education , polymerization
N , N ′‐Diphenyl‐ p ‐benzoquinonediimine, a redox‐active unit of polyaniline, efficiently induced the oxidative homocoupling of various aryl‐ and vinylmagnesium reagents in suppressing the side reactions, such as 1,2‐ or 1,4‐addition reaction.