Premium
Ligand Self‐Sorting and Nonlinear Effects in Dinuclear Asymmetric Hydrogenation: Complexity in Catalysis
Author(s) -
Terrade Frédéric G.,
Lutz Martin,
Reek Joost N. H.
Publication year - 2013
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201301966
Subject(s) - sorting , asymmetric hydrogenation , nonlinear system , computer science , scheme (mathematics) , ligand (biochemistry) , solubility , substrate (aquarium) , chemistry , combinatorial chemistry , information retrieval , catalysis , enantioselective synthesis , mathematics , algorithm , organic chemistry , physics , biochemistry , biology , mathematical analysis , ecology , receptor , quantum mechanics
Self‐sorting species : Nonlinear effects are observed in asymmetric hydrogenation reactions if self‐sorted dinuclear complexes are generated. The nature of the substrate also influences this effect, because it affects the solubility of racemic self‐sorted homochiral dinuclear complexes (see scheme).