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Versatile Post‐functionalization of Polyoxometalate Platforms By Using An Unprecedented Range of Palladium‐Catalyzed Coupling Reactions
Author(s) -
Lorion Mélanie M.,
Matt Benjamin,
Alves Sandra,
Proust Anna,
Poli Giovanni,
Oble Julie,
Izzet Guillaume
Publication year - 2013
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201301694
Subject(s) - polyoxometalate , palladium , surface modification , catalysis , substrate (aquarium) , coupling reaction , coupling (piping) , combinatorial chemistry , materials science , chemistry , nanotechnology , organic chemistry , composite material , oceanography , geology
Handy POMs : Several palladium‐catalyzed coupling reactions have been applied to polyoxometalate post‐functionalization. The feasibility of each reaction with one model substrate was investigated and each set of synthetic conditions was optimized to obtain full conversions and high purity hybrid compounds (see scheme).