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Palladium‐Catalyzed Skeletal Rearrangement of Spirotricyclic Olefins: A Facile One‐Pot Strategy for the Synthesis of a Novel Motif with Cyclopentene Fused to Benzofuran and Pyrazolidine
Author(s) -
Prakash Praveen,
Jijy Eliyan,
Preethanuj Preethalayam,
Pihko Petri M.,
Sarath Chand Sarngadharan,
Radhakrishnan Kokkuvayil V.
Publication year - 2013
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201301475
Subject(s) - benzofuran , palladium , catalysis , combinatorial chemistry , cyclopropane , chemistry , cyclopentene , computer science , stereochemistry , organic chemistry , ring (chemistry)
Complex molecule synthesis : An efficient one‐pot strategy for the synthesis of a novel framework of benzofuran‐pyrazolidine‐fused cyclopentenes by a palladium‐catalyzed tandem reaction of cyclopropane‐bearing spirotricyclic olefins with 2‐iodophenols is reported (see scheme).