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Lanthanide Oxide Clusters: From Tetrahedral [Dy 4 (μ 4 ‐O)] 10+ to Supertetrahedral [Ln 20 (μ 4 ‐O) 11 ] 38+ (Ln=Tb, Dy, Ho, Er)
Author(s) -
Lin WeiQuan,
Liao XiaoFen,
Jia JianHua,
Leng JiDong,
Liu JunLiang,
Guo FuSheng,
Tong MingLiang
Publication year - 2013
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201301397
Subject(s) - lanthanide , crystallography , oxide , tetrahedron , chemistry , physics , materials science , ion , metallurgy , organic chemistry
Supertetrahedral clusters : A family of lanthanide oxide supertetrahedral T 3 {Ln 20 } clusters (Ln=Tb, Dy, Ho, Er; see figure) were obtained from the solvothermal reaction of lanthanide(III) salts with polytriazolate ligands that could be methylated and oxidized in situ.