Salimabromide: Unexpected Chemistry from the Obligate Marine Myxobacterium  Enhygromyxa salina | Zendy

Felder Stephan | Zendy; Dreisigacker Sandra | Zendy; Kehraus Stefan | Zendy; Neu Edith | Zendy; Bierbaum Gabriele | Zendy; Wright Patrick R. | Zendy; Menche Dirk | Zendy; Schäberle Till F. | Zendy; König Gabriele M. | Zendy

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Salimabromide: Unexpected Chemistry from the Obligate Marine Myxobacterium Enhygromyxa salina

Author(s) -

Felder Stephan,

Dreisigacker Sandra,

Kehraus Stefan,

Neu Edith,

Bierbaum Gabriele,

Wright Patrick R.,

Menche Dirk,

Schäberle Till F.,

König Gabriele M.

Publication year - 2013

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201301379

Subject(s) - myxobacteria , stereochemistry , chemistry , natural product , ring (chemistry) , moiety , carbon skeleton , absolute configuration , residue (chemistry) , organic chemistry , biology , bacteria , paleontology

Marine myxobacteria ( Enhygromyxa , Plesiocystis , Pseudoenhygromyxa , Haliangium ) are phylogenetically distant from their terrestrial counterparts. Salimabromide is the first natural product from the Plesiocystis / Enhygromyxa clade of obligatory marine myxobacteria. Salimabromide has a new tetracyclic carbon skeleton, comprising a brominated benzene ring, a furano lactone residue, and a cyclohexane ring, bridged by a seven‐membered cyclic moiety. The absolute configuration was deduced from experimental and calculated CD data. Salimabromide revealed antibiotic activity towards Arthrobacter cristallopoietes .

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