Redox‐Selective Generation of Aldehydes and H 2  from Alcohols under Visible Light | Zendy

Liu Zijun | Zendy; Caner Joaquim | Zendy; Kudo Akihiko | Zendy; Naka Hiroshi | Zendy; Saito Susumu | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Redox‐Selective Generation of Aldehydes and H 2 from Alcohols under Visible Light

Author(s) -

Liu Zijun,

Caner Joaquim,

Kudo Akihiko,

Naka Hiroshi,

Saito Susumu

Publication year - 2013

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201301347

Subject(s) - dehydrogenation , aldehyde , selectivity , redox , chemistry , photochemistry , visible spectrum , catalysis , organic chemistry , materials science , optoelectronics

Photosynthetic dehydrogenation : Potential usefulness of visible‐light‐induced dehydrogenation of alcohols in organic synthesis was demonstrated, in which aldehydes and H 2 were afforded by using Ru/SrTiO 3 :Rh and water (see scheme). Water was essential for the reaction. High efficiency (TON: up to 15 400 based on Rh; H 2 and aldehyde evenly generated) and high selectivity were achieved.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research