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Catalysis with Gold Complexes Immobilised on Carbon Nanotubes by π–π Stacking Interactions: Heterogeneous Catalysis versus the Boomerang Effect
Author(s) -
Vriamont Charles,
Devillers Michel,
Riant Olivier,
Hermans Sophie
Publication year - 2013
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201300998
Subject(s) - stacking , catalysis , carbon nanotube , nanotechnology , materials science , chemistry , chemical engineering , organic chemistry , engineering
A new pyrene‐tagged gold(I) complex has been synthesised and tested as a homogeneous catalyst. First, a simple 1,6‐enyne was chosen as a model substrate for cyclisation by using different solvents to optimise the reaction conditions. The non‐covalent immobilisation of our pyrene‐tagged gold complex onto multi‐walled carbon nanotubes through π–π stacking interactions was then explored to obtain a supported homogeneous catalyst. The heterogenised catalyst and its homogeneous counterpart exhibited similar activity in a range of enyne cyclisation reactions. Bearing in mind that π–π interactions are affected by temperature and solvent polarity, the reuse and robustness of the supported homogeneous catalyst was tested to explore the scope and limitations of the recyclability of this catalyst. Under the optimised conditions, recyclability was observed by using the concept of the boomerang effect.