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Na 11 B 21 O 36 X 2 (X=Cl, Br): Halogen Sodium Borates with a New Graphene‐Like Borate Double Layer
Author(s) -
Dong Xiaoyu,
Wu Hongping,
Shi Yunjing,
Yu Hongwei,
Yang Zhihua,
Zhang Bingbing,
Chen Zhaohui,
Yang Yun,
Huang Zhenjun,
Pan Shilie,
Zhou Zhongxiang
Publication year - 2013
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201300902
Subject(s) - boron , graphene , halogen , cleavage (geology) , inorganic chemistry , layer (electronics) , materials science , ionic bonding , ion , crystallography , chemistry , nanotechnology , organic chemistry , composite material , alkyl , fracture (geology)
Borate not graphene : The [B 6 O 12 ] ∞ 6− single borate layer is a graphene‐like layer (see figure). The weak Na + Br(Cl) − ionic connection between the layers leads to the layer cleavage, and difficulty of the block crystal growth.