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Simultaneous Fragmentation and Activation of White Phosphorus
Author(s) -
Arnold Thomas,
Braunschweig Holger,
JimenezHalla J. Oscar C.,
Radacki Krzysztof,
Sen Sakya S.
Publication year - 2013
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201300895
Subject(s) - white phosphorus , fragmentation (computing) , computer science , molybdenum , chemistry , world wide web , phosphorus , programming language , inorganic chemistry , organic chemistry
Mo and Si in concert : Fragmentation and simultaneous activation of white phosphorus was achieved by a complex featuring reactive main‐group‐element and transition‐metal sites. The unusual electronic structure of the resulting tricyclic molybdenum complex (see figure) was elucidated experimentally and computationally.