Premium
Tetrathiafulvalene‐Annulated Subphthalocyanines
Author(s) -
Shimizu Soji,
Yamazaki Yoko,
Kobayashi Nagao
Publication year - 2013
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201300709
Subject(s) - tetrathiafulvalene , quenching (fluorescence) , photochemistry , absorption (acoustics) , fluorescence , electrochemistry , materials science , chemistry , organic chemistry , molecule , optics , electrode , physics , composite material
Peripheral expansion : A series of peripherally tetrathiafulvalene (TTF)‐annulated subphthalocyanines was synthesized (see scheme). These compounds exhibited unique perturbed optical properties, such as a comparatively broad Q band absorption and gradual quenching of fluorescence upon increasing the number of TTF units, while electrochemical measurements revealed TTF‐centered oxidation processes.