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Nickel‐Catalysed Hydroalkoxylation Reaction of 1,3‐Butadiene: Ligand Controlled Selectivity for the Efficient and Atom‐Economical Synthesis of Alkylbutenyl Ethers
Author(s) -
Bigot Sandra,
El Alami Mohammed Samir Ibn,
Mifleur Alexis,
Castanet Yves,
Suisse Isabelle,
Mortreux André,
Sauthier Mathieu
Publication year - 2013
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201300633
Subject(s) - nickel , catalysis , butane , chemistry , selectivity , ligand (biochemistry) , 1,3 butadiene , medicinal chemistry , atom (system on chip) , combinatorial chemistry , organic chemistry , computer science , biochemistry , receptor , embedded system
The nickel‐catalysed hydroalkoxylation of butadiene is promoted by a nickel(0)/dppb catalyst (dppb=1,4‐bis(diphenylphosphino)butane; see scheme). By following this new synthetic procedure, alkylbutenyl ethers are readily obtained from an alcohol and 1,3‐butadiene with exclusion of dimerisation and telomerisation products.