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Experimental Evidences in Favour of the Hydroxylamine→Nitrene–Water Tautomerization on the Coordination Sphere of Ir III Centres
Author(s) -
Cristóbal Crispín,
LópezSerrano Joaquín,
LozanoVila Ana M.,
Paneque Margarita,
Poveda Manuel L.,
Vattier Florencia,
Vivancos Ángela,
Álvarez Eleuterio
Publication year - 2013
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201300624
Subject(s) - hydroxylamine , tautomer , nitrene , coordination sphere , chemistry , coordination complex , stereochemistry , computational chemistry , crystallography , organic chemistry , crystal structure , catalysis , metal
And, to round off … A series of Ir III 5‐membered metallacycles with an IrCH 2 bond, react with aq. NH 2 OH with formation of hydride 6‐membered iridacyclic complexes, which contain an IrNHCH imine functionality (see scheme).