Versatile Reactivity of a Lithium Tris(aryl)plumbate(II) Towards Organolanthanoid Compounds: Stable Lead–Lanthanoid–Metal Bonds or Redox Processes | Zendy

Zeckert Kornelia | Zendy; Griebel Jan | Zendy; Kirmse Reinhard | Zendy; Weiß Michael | Zendy; Denecke Reinhard | Zendy

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Versatile Reactivity of a Lithium Tris(aryl)plumbate(II) Towards Organolanthanoid Compounds: Stable Lead–Lanthanoid–Metal Bonds or Redox Processes

Author(s) -

Zeckert Kornelia,

Griebel Jan,

Kirmse Reinhard,

Weiß Michael,

Denecke Reinhard

Publication year - 2013

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201300596

Subject(s) - lanthanide , redox , tris , lithium (medication) , europium , chemistry , ligand (biochemistry) , reactivity (psychology) , combinatorial chemistry , aryl , divalent , metal , inorganic chemistry , organic chemistry , ion , biochemistry , pathology , endocrinology , medicine , alkyl , receptor , alternative medicine

Redox chemistry : Redox‐active europium complexes based on a new tris(2‐pyridyl)plumbate ligand are described. Reactions of [LiPb(2‐py R ) 3 (thf)] (py R = C 5 H 3 ‐6‐O t Bu) with tri‐ or divalent lanthanoid metals resulted in the first stable Pb–Ln‐bonded complexes or unprecedented redox reactions, involving, for example, the pentametallic complex depicted.

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