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Pyracene‐Linked Bis‐Imidazolylidene Complexes of Palladium and Some Catalytic Benefits Produced by Bimetallic Catalysts
Author(s) -
GuisadoBarrios Gregorio,
Hiller Joanna,
Peris Eduardo
Publication year - 2013
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201300486
Subject(s) - aryl , palladium , catalysis , halide , chemistry , bimetallic strip , carbene , acylation , polymer chemistry , suzuki reaction , combinatorial chemistry , medicinal chemistry , organic chemistry , alkyl
Two new palladium complexes with a pyracene‐linked bis‐imidazolylidene (pyrabim) group have been obtained and fully characterized. The related monometallic analogues were obtained from the coordination of an acetanaphthene‐supported N‐heterocyclic carbene (NHC). The catalytic properties of all complexes were studied in the acylation of aryl halides with hydrocinnamaldehyde, and in the Suzuki–Miyaura coupling of aryl halides and aryl boronic acids. The results show that the presence of a second metal in the dimetallic complexes induces some benefits in the catalytic behavior of the complexes. This effect is more pronounced in the Suzuki–Miyaura coupling, for which the dimetallic complexes exhibit significantly higher activity than their monometallic counterparts.