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Unprecedented Multi‐Stable Spin Crossover Molecular Material with Two Thermal Memory Channels
Author(s) -
Seredyuk Maksym,
Muñoz M. Carmen,
Castro Miguel,
RomeroMorcillo Tania,
Gaspar Ana B.,
Real Jose Antonio
Publication year - 2013
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201300394
Subject(s) - spin crossover , crossover , thermal , materials science , spin (aerodynamics) , nanotechnology , condensed matter physics , physics , computer science , thermodynamics , artificial intelligence
Two in one : A new iron(II) complex with short alkyl substituents exhibits an unprecedented bimodal behavior governed by the coexistence of three phases: two structurally different low‐spin phases and one high‐spin phase. The compound features two distinct well‐separated strong cooperative spin‐crossover transitions by varying the scan rate (see graphic).