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Twofold Carbon–Carbon Bond Formation by Intra‐ and Intermolecular Radical Reactions of Aryl Diazonium Salts
Author(s) -
Jasch Hannelore,
Landais Yannick,
Heinrich Markus R.
Publication year - 2013
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201300354
Subject(s) - chemistry , aryl , intermolecular force , cascade , salt (chemistry) , aryl radical , diazonium compounds , radical , carbon fibers , photochemistry , organic chemistry , molecule , alkyl , materials science , chromatography , composite number , composite material
Cascade reactions : A variety of novel cascade reactions can be performed when the known and well‐studied radical 5‐ or 6‐ exo ‐cyclization of an aryl diazonium salt is conducted in the presence of alkenes and further optional scavengers (see scheme).