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Cobalt‐Catalyzed Electrophilic Amination of Arylzincs with N ‐Chloroamines
Author(s) -
Qian Xin,
Yu Zailu,
Auffrant Audrey,
Gosmini Corinne
Publication year - 2013
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201300229
Subject(s) - electrophilic amination , amination , cobalt , electrophile , reagent , variety (cybernetics) , computer science , catalysis , chemistry , combinatorial chemistry , operations research , organic chemistry , engineering , artificial intelligence
Roles reversed : An efficient cobalt‐catalyzed electrophilic amination of arylzinc reagents has been achieved. A variety of functionalized arylzincs and N ‐chloroamines were coupled under mild conditions (see scheme). Both secondary and tertiary arylamines were obtained in moderate to excellent yields.
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