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Cover Picture: Pressure‐Induced Enhancement of Magnetic‐Ordering Temperature in an Organic Radical to 70 K: A Magnetostructural Correlation (Chem. Eur. J. 28/2012)
Author(s) -
Thomson Richard I.,
Pask Christopher M.,
Lloyd Gareth O.,
Mito Masaki,
Rawson Jeremy M.
Publication year - 2012
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201290115
Subject(s) - nanofiber , supramolecular chemistry , intermolecular force , chromophore , diimide , chemistry , crystallography , crystal engineering , materials science , nanotechnology , crystal structure , organic chemistry , perylene , molecule
The organic radical β‐ p ‐NCC 6 F 4 CNSSN . exhibited an enhancement in magnetic‐ordering temperature to 70 K under pressure. Structure solution from variable pressure powder X‐ray diffraction (PXRD) studies coupled with DFT calculations revealed a strong magnetostructural correlation between the intermolecular S ⋅⋅⋅ N contacts and magnetic‐ordering temperature. For more details, see the Full Paper by J. M. Rawson et al. on page 8629 ff.