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Palladium‐Catalyzed Oxidative Regio‐ and Diastereoselective Diarylating Carbocyclization of Dienynes
Author(s) -
Jiang Min,
Bäckvall JanE.
Publication year - 2013
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201204555
Subject(s) - transmetalation , palladium , catalysis , chemistry , oxidative phosphorylation , conjugated system , conjugated diene , triple bond , diene , combinatorial chemistry , double bond , organic chemistry , biochemistry , natural rubber , monomer , polymer
Transmetallation : A highly regio‐ and diastereoselective carbocyclization involving a palladium‐catalyzed 1,2‐addition of two carbon atoms across a conjugated diene has been developed (see scheme). The reaction is performed with dienynes and an oxygen tether containing a terminal or internal triple bond.