Development of Metal/Organo Catalytic Systems for Direct Vinylogous Michael Reactions to Build Chiral γ,γ‐Disubstituted Butenolides | Zendy

Yang Dongxu | Zendy; Wang Linqing | Zendy; Zhao Depeng | Zendy; Han Fengxia | Zendy; Zhang Bangzhi | Zendy; Wang Rui | Zendy

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Development of Metal/Organo Catalytic Systems for Direct Vinylogous Michael Reactions to Build Chiral γ,γ‐Disubstituted Butenolides

Author(s) -

Yang Dongxu,

Wang Linqing,

Zhao Depeng,

Han Fengxia,

Zhang Bangzhi,

Wang Rui

Publication year - 2013

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201204466

Subject(s) - dual (grammatical number) , conjugate , catalysis , computer science , aryl , metal , chemistry , combinatorial chemistry , alkyl , organic chemistry , philosophy , mathematics , mathematical analysis , linguistics

Vinylogous reactions : The direct asymmetric vinylogous conjugate additions of γ‐aryl‐ and alkyl‐substituted butenolides to enones was realized for the first time by a designed and tested metal/organo dual‐activation strategy, in which two effective metal/organo cooperative catalytic systems have been built (see scheme).

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