Rhodium‐Catalyzed Carbocyclization and Chlorosulfonylation of 1,6‐Enynes with Sulfonyl Chlorides | Zendy

Chen Chen | Zendy; Su Jianhua | Zendy; Tong Xiaofeng | Zendy

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Rhodium‐Catalyzed Carbocyclization and Chlorosulfonylation of 1,6‐Enynes with Sulfonyl Chlorides

Author(s) -

Chen Chen,

Su Jianhua,

Tong Xiaofeng

Publication year - 2013

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201204039

Subject(s) - rhodium , sulfonyl , catalysis , chemistry , element (criminal law) , ferrocene , combinatorial chemistry , computer science , medicinal chemistry , organic chemistry , law , political science , electrode , electrochemistry , alkyl

Linked in : A rhodium(I) catalyst system [[Rh(cod)Cl]+DPPF] enables carbocyclization and chlorosulfonylation of 1,6‐enynes with sulfonyl chlorides, thus allowing the formation of three different bonds (CCl, CC, and CS) in a one‐step fashion (see scheme; cod=cyclooctadiene, DPPF=1,1′‐bis(diphenylphosphino)ferrocene). Sulfonyl chlorides are shown to be an efficient linker in this transformation, which complements other known element–element linkers.

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