A Neutral, Chiral, Bis(imidazolidine)‐Derived NCN‐Type Palladium Pincer Complex with Catalytic Activity | Zendy

Arai Takayoshi | Zendy; Oka Ikiyo | Zendy; Morihata Takuma | Zendy; Awata Atsuko | Zendy; Masu Hyuma | Zendy

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A Neutral, Chiral, Bis(imidazolidine)‐Derived NCN‐Type Palladium Pincer Complex with Catalytic Activity

Author(s) -

Arai Takayoshi,

Oka Ikiyo,

Morihata Takuma,

Awata Atsuko,

Masu Hyuma

Publication year - 2013

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201204017

Subject(s) - pincer movement , imidazolidine , palladium , catalysis , enantioselective synthesis , chemistry , ligand (biochemistry) , malononitrile , single crystal , coordination sphere , combinatorial chemistry , medicinal chemistry , organic chemistry , crystal structure , crystallography , biochemistry , receptor

Caught in a pincer : A chiral, imidazolidine‐derived NCN‐type palladium pincer complex has been prepared using a ligand introduction technique. Single‐crystal X‐ray diffraction analysis of this complex showed a well‐organized asymmetric sphere. The neutral palladium/chloride version exhibited significant catalytic activity for the reaction of nitroalkenes with malononitrile to give products in a highly enantioselective manner (see scheme).

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