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From Cyclopropenes to Tetrasubstituted Furans: Tandem Isomerization/Alkenylation Sequence with Cu/Pd Relay Catalysis
Author(s) -
Song Chuanling,
Ju Lin,
Wang Mingchao,
Liu Pengcheng,
Zhang Yuanzhe,
Wang Jianwu,
Xu Zhenghu
Publication year - 2013
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201203997
Subject(s) - isomerization , tandem , relay , sequence (biology) , catalysis , alkene , combinatorial chemistry , computer science , chemistry , cascade , organic chemistry , physics , materials science , power (physics) , biochemistry , quantum mechanics , composite material , chromatography
Pon de relay : A convenient and efficient synthesis of alkene‐functionalized furans from cyclopropenes, which proceeds through an isomerization/olefination cascade sequence under copper–palladium relay catalysis, has been developed (see scheme).