CC Bond Cleavage of Zwitterionic Carboranes Promoted by a Half‐Sandwich Iridium(III) Complex | Zendy

Yao ZiJian | Zendy; Lin YueJian | Zendy; Li ZhenHua | Zendy; Jin GuoXin | Zendy

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CC Bond Cleavage of Zwitterionic Carboranes Promoted by a Half‐Sandwich Iridium(III) Complex

Author(s) -

Yao ZiJian,

Lin YueJian,

Li ZhenHua,

Jin GuoXin

Publication year - 2013

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201203850

Subject(s) - iridium , cleavage (geology) , bond cleavage , chemistry , scheme (mathematics) , combinatorial chemistry , computer science , nanotechnology , materials science , catalysis , organic chemistry , mathematics , mathematical analysis , fracture (geology) , composite material

Open‐and‐shut case : The cage CC bond cleavage of monosubstituted carborane derivatives at room temperature has now been achieved. This approach, which is facilitated by half‐sandwich complexes, provides a facile and direct synthesis of pseudocloso metallacarboranes (see scheme; dots indicate carbon atoms).

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