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Titanium‐Catalyzed Intermolecular Hydroaminoalkylation of Conjugated Dienes
Author(s) -
Preuß Till,
Saak Wolfgang,
Doye Sven
Publication year - 2013
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201203693
Subject(s) - conjugated system , intermolecular force , catalysis , titanium , atom (system on chip) , computer science , chemistry , service (business) , combinatorial chemistry , organic chemistry , molecule , business , polymer , marketing , embedded system
Ti me kangaroo down : Conjugated dienes undergo intermolecular hydroaminoalkylation in the presence of Ti catalyst [Ind 2 TiMe 2 ] (Ind=η 5 ‐indenyl). This new reaction offers a highly atom‐efficient approach to homoallylic amines from 1,3‐butadienes.
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