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Crystalline Structural Intermediates of a Breathing Metal–Organic Framework That Functions as a Luminescent Sensor and Gas Reservoir
Author(s) -
Xiao Juan,
Wu Yuan,
Li Mian,
Liu BaoYu,
Huang XiaoChun,
Li Dan
Publication year - 2013
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201203515
Subject(s) - benzotriazole , set (abstract data type) , sorption , computer science , breathing , luminescence , metal organic framework , feature (linguistics) , materials science , database , chemistry , optoelectronics , organic chemistry , programming language , philosophy , psychology , adsorption , linguistics , psychiatry
A rod‐packing, breathing MOF ( 1 ), with two crystalline structural intermediates ( 1 a and 1 b ; H 2 btca=benzotriazole‐5‐carboxylic acid) has been investigated. An underlying net approach for analyzing possible breathing MOFs, and a set of geometric parameters that can quantitatively describe such a breathing structural feature, are suggested. The 3D luminescent MOF is a promising candidate for specific sensors with exceptional sorption capacity.