Crystalline Structural Intermediates of a Breathing Metal–Organic Framework That Functions as a Luminescent Sensor and Gas Reservoir | Zendy

Xiao Juan | Zendy; Wu Yuan | Zendy; Li Mian | Zendy; Liu BaoYu | Zendy; Huang XiaoChun | Zendy; Li Dan | Zendy

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Crystalline Structural Intermediates of a Breathing Metal–Organic Framework That Functions as a Luminescent Sensor and Gas Reservoir

Author(s) -

Xiao Juan,

Wu Yuan,

Li Mian,

Liu BaoYu,

Huang XiaoChun,

Li Dan

Publication year - 2013

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201203515

Subject(s) - benzotriazole , set (abstract data type) , sorption , computer science , breathing , luminescence , metal organic framework , feature (linguistics) , materials science , database , chemistry , optoelectronics , organic chemistry , programming language , philosophy , psychology , adsorption , linguistics , psychiatry

A rod‐packing, breathing MOF ( 1 ), with two crystalline structural intermediates ( 1 a and 1 b ; H 2 btca=benzotriazole‐5‐carboxylic acid) has been investigated. An underlying net approach for analyzing possible breathing MOFs, and a set of geometric parameters that can quantitatively describe such a breathing structural feature, are suggested. The 3D luminescent MOF is a promising candidate for specific sensors with exceptional sorption capacity.

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