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Ag/AgBr/Co–Ni–NO 3 Layered Double Hydroxide Nanocomposites with Highly Adsorptive and Photocatalytic Properties
Author(s) -
Fan Hai,
Zhu Jianying,
Sun Jianchao,
Zhang Shenxiang,
Ai Shiyun
Publication year - 2013
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201203408
Subject(s) - nanocomposite , photocatalysis , methyl orange , hydroxide , materials science , adsorption , layered double hydroxides , bifunctional , ion exchange , chemical engineering , coprecipitation , activated carbon , nanoparticle , inorganic chemistry , chemistry , nanotechnology , catalysis , ion , organic chemistry , engineering
A facile anion‐exchange precipitation method was used to synthesize bifunctional Ag/AgBr/Co–Ni–NO 3 layered double hydroxide (LDH) nanocomposites by adding AgNO 3 solution to a suspension of Co–Ni–Br LDH. The Ag/AgBr nanoparticles were highly dispersed on the sheets of Co–Ni–NO 3 LDH. The prepared nanocomposites were used to adsorb and photocatalytically degrade organic pollutants from water. Without light illumination, the nanocomposites quickly adsorbed methyl orange, and the adsorptive capacity, which can reach 230 mg g −1 , is much higher than those of Co–Ni–Br LDH, Ag/AgBr, and activated carbon. The photocatalytic activities of the nanocomposites for the removal of dyes and phenol are higher than those of Co–Ni–Br LDH and Ag/AgBr. The proposed method can be applied to prepare other LDH/silver salt composites. The high absorptive capacity and good photocatalytic activity of such nanostructures could have wide applications in wastewater treatment.