Premium
Mild Reduction of Carbon Dioxide to Methane with Tertiary Silanes Catalyzed by Platinum and Palladium Silyl Pincer Complexes
Author(s) -
Mitton Samuel J.,
Turculet Laura
Publication year - 2012
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201203226
Subject(s) - silanes , silylation , palladium , catalysis , methane , chemistry , platinum , pincer movement , carbon dioxide , reduction (mathematics) , organic chemistry , inorganic chemistry , silane , mathematics , geometry
Pincing CO 2 : Group 10 (Pd, Pt) silyl pincer complexes in combination with B(C 6 F 5 ) 3 can facilitate the efficient catalytic conversion of CO 2 to methane with a tertiary silane as the reductant under mild conditions. The reduction involves the formation of Pd and Pt formatoborate complexes.