Highly Enantioselective Imine Hydrogenation Catalyzed by Ruthenium Phosphane–Phosphite Diamine Complexes | Zendy

Vaquero Mónica | Zendy; Suárez Andrés | Zendy; Vargas Sergio | Zendy; Bottari Giovanni | Zendy; Álvarez Eleuterio | Zendy; Pizzano Antonio | Zendy

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Highly Enantioselective Imine Hydrogenation Catalyzed by Ruthenium Phosphane–Phosphite Diamine Complexes

Author(s) -

Vaquero Mónica,

Suárez Andrés,

Vargas Sergio,

Bottari Giovanni,

Álvarez Eleuterio,

Pizzano Antonio

Publication year - 2012

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201203193

Subject(s) - enantioselective synthesis , imine , ruthenium , diamine , catalysis , ligand (biochemistry) , chemistry , combinatorial chemistry , aryl , organic chemistry , noyori asymmetric hydrogenation , biochemistry , alkyl , receptor

Mildly does it : A highly enantioselective catalyst for the hydrogenation of N ‐aryl imines is described (see scheme). This catalyst offers practical advantages because it operates under very mild conditions and is based on an Ru complex with a diamine as the sole chiral ligand.

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