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Synthesis of Complexes Containing an Anionic NHC Ligand with an Unsubstituted Ring‐Nitrogen Atom
Author(s) -
Kösterke Tim,
Kösters Jutta,
Würthwein ErnstUlrich,
MückLichtenfeld Christian,
Schulte to Brinke Christian,
Lahoz Fernando,
Hahn F. Ekkehardt
Publication year - 2012
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201202973
Subject(s) - ligand (biochemistry) , nitrogen atom , chemistry , ring (chemistry) , nitrogen , nucleophile , medicinal chemistry , atom (system on chip) , oxidative addition , oxidative phosphorylation , stereochemistry , organic chemistry , catalysis , receptor , biochemistry , computer science , embedded system
Oxidative addition : Complexes containing an anionic NHC ligand with an unsubstituted nitrogen atom within the heterocycle have been prepared by oxidative addition of 2‐chloro‐ N ‐methylbenzimidazole to Ni 0 and Pt 0 (see scheme). The “naked” nitrogen atom of the NHC ligand reacts as a strong nucleophile.
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