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A Selective Palladium‐Catalyzed Carbonylative Arylation of Aryl Ketones to Give Vinylbenzoate Compounds
Author(s) -
Schranck Johannes,
Tlili Anis,
Neumann Helfried,
Alsabeh Pamela G.,
Stradiotto Mark,
Beller Matthias
Publication year - 2012
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201202895
Subject(s) - aryl , palladium , halide , catalysis , benzoates , chemistry , organic chemistry , medicinal chemistry , carbonylation , carbon monoxide , alkyl
Preparation of enols : When treated with [{Pd(cinnamyl)Cl} 2 ]/cataCXium A ( n BuPAd 2 , Ad=adamantyl) under an atmosphere of CO, aryl ketones react with aryl halides in a carbonylative CO coupling reaction to form ( Z )‐vinyl benzoates (see scheme).