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Cross‐Linked Helically Chiral Poly‐(γ‐benzyl‐ L ‐glutamate) as Enantiodiscriminating Alignment Medium
Author(s) -
Montag Tobias,
Thiele Christina M.
Publication year - 2013
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201202554
Subject(s) - polymer , materials science , glutamate receptor , chemistry , polymer chemistry , stereochemistry , composite material , biochemistry , receptor
The best of both worlds : By crosslinking poly‐(γ‐benzyl‐ L ‐glutamate) (PBLG), an alignment medium, which combines the scalability of cross‐linked polymer gels (strain‐induced‐alignment media) with the enantiodiscriminating properties of helically chiral PBLG, was obtained. Spectra of excellent quality and residual dipolar couplings (RDCs) of the perfect size can be obtained for small organic compounds (see scheme; Bn=benzyl).