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The Synthesis of Organometallic Coordination Polymer Flowers of Prussian Blue with Ultrathin Petals by Using Crystallization‐Assisted Interface Coordination Polymerization (CAICP)
Author(s) -
Bao Suping,
Liu Tingting,
Liang Guodong,
Gao Haiyang,
Zhu Fangming,
Wu Qing
Publication year - 2012
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201202395
Subject(s) - prussian blue , petal , polymer , polymerization , coordination polymer , thermal stability , nanotechnology , materials science , photoluminescence , crystallization , computer science , chemistry , optoelectronics , organic chemistry , botany , biology , electrode , composite material , electrochemistry
Tiny flowers : A conceptually new method for fabricating polymer/Prussian blue (PB) hybrid flowers with ultrathin petals by using a CAICP technique has been developed. The PB hybrid flowers exhibit enhanced thermal stability, emit deep‐blue light, and are electrochemically active. Their intriguing microstructure and enhanced structure‐dependent properties make them potentially useful in nanodevices, biosensors, and photoluminescent devices.