Zeolitic Boron Imidazolate Frameworks with 4‐Connected Octahedral Metal Centers | Zendy

Wang Fei | Zendy; Shu YuBo | Zendy; Bu Xianhui | Zendy; Zhang Jian | Zendy

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Zeolitic Boron Imidazolate Frameworks with 4‐Connected Octahedral Metal Centers

Author(s) -

Wang Fei,

Shu YuBo,

Bu Xianhui,

Zhang Jian

Publication year - 2012

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201202377

Subject(s) - imidazolate , octahedron , zeolitic imidazolate framework , boron , selectivity , tetrahedron , metal organic framework , chemistry , metal , materials science , crystallography , inorganic chemistry , adsorption , crystal structure , organic chemistry , catalysis

Solvent selection! The organically templated co‐assembly between tetrahedral [B(imidazolate) 4 ] − and [Co(ac)] + units leads to two previously unknown zeolitic boron imidazolate frameworks with ACO and ABW topologies (denoted BIF‐22 and BIF‐23 ; e‐urea=ethyleneurea), respectively. BIF‐22 is chiral and shows interesting CO 2 selectivity over N 2 and CH 4 .

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